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And why, praytell would you not soft solder it? You're fixing a leak on a 80-100 psi boiler, which is well within the capabilities of a lead bearing soft solder to remain as a solid with enough strength to act as a caulk.
I have a boiler downstairs that is completely soft soldered. (and stayed, so the soft solder is strictly a caulking). It was a fairly common pre ww2 method of building boilers, particularly for 60 psi or under. If the boiler is a 125 psi job, then I would be more tempted to reach for oxy, but...if you re silver solder it, expect that you will move the leak around rather than fixing it.
The important concern from where I sit is that the soft solder must be purely seen as a caulking medium, and not providing any strength at all.
Been there, got the T-Shirt, and have a couple of boilers where soft solder has been used as a caulk, and one engine where someone used soft solder where he should have used silver, and that causes me grief. (the injector occasionally just falls off...)
I will note though, that once you soft solder on the boiler you will NEVER be able to silver solder in the same area. The lead/tin (I understand the lead) will prevent silver solder from penetrating the surface metal & so silver solder will no longer be a useable cure around that area.
James Powell
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